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Synthesis of a Highly Unsaturated, Stable Hydroxy Peroxide: A Yellow reversible arrow Blue Color-Changing Carotenoid Oxidation Product with Leuco Dye Properties

  作者 LI HE; REBMANN EDOUARD; OPSTAD CHRISTER L; SCHMID RUDOLF; SLIWKA HANSRICHARD; PARTALI VASSILIA  
  选自 期刊  European Journal of Organic Chemistry;  卷期  2010年-24;  页码  4630-4636  
  关联知识点  
 

[摘要]A stable, highly unsaturated hydroxy peroxide was synthesized by reacting a common food color carotenoid with FeC1(3) in air. The obtained pale-yellow carotenoid hydroxy peroxide is easily converted into a blue, cationic polyene - then changes back to the yellow compound, showing the same characteristically dichromic properties like polycyclic, aromatic leuco dyes.

 
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