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Highly Selective Ylide-Initiated Michael Addition/Cyclization Reaction for Synthesis of Cyclohexadiene Epoxide and Vinylcyclopropane Derivatives

  作者 ZHU BENHU; ZHOU RUI; ZHENG JUNCHENG; DENG XIANMING; SUN XIULI; SHEN QI; TANG YONG  
  选自 期刊  Journal of Organic Chemistry;  卷期  2010年75-10;  页码  3454-3457  
  关联知识点  
 

[摘要]On the basis of the reactions of camphor-derived sulfur ylide with alpha,beta-unsaturated ketone, highly efficient and selective synthesis of optically active cyclohexadiene epoxides and vinylcyclopropanes with excellent diastereoselectivities, moderate to high enantioselectivities, and yields has been achieved.

 
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