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Chromene "Lock", Thiol "Key", and Mercury(II) Ion "Hand": A Single Molecular Machine Recognition System

  作者 HUO FANGJUN; SUN YUANQIANG; SU JING; YANG YUTAO; YIN CAIXIA; CHAO JIANBIN  
  选自 期刊  Organic Letters;  卷期  2010年12-21;  页码  4756-4759  
  关联知识点  
 

[摘要]A regenerative, molecular machine-like "ON-OFF-ON" chemosensor based on a chromene molecule with the pyran ring "OFF-ON-OFF" cycle is reported for the first time. It behaves as a molecular lock that requires a thiol "key" to open the lock and a mercury(II) ion "hand" that unlatches the key for unsheathing the key to close the lock.

 
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