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Gold-Catalyzed Oxidative Coupling Reactions with Aryltrimethylsilanes

  作者 BRENZOVICH WILLIAM E JR; BRAZEAU JEANFRANCOIS; TOSTE F DEAN  
  选自 期刊  Organic Letters;  卷期  2010年12-21;  页码  4728-4731  
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[摘要]During continuing studies with a novel oxidative gold oxyarylation reaction, arylsilanes were found to be competent coupling partners, providing further evidence for an intramolecular electrophilic aromatic substitution mechanism. While providing yields complementary to those of the previously described boronic acid methods, the use of trimethylsilanes reduces the observation of homocoupling byproducts and allows for facile intramolecular coupling reactions.

 
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