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Synthesis of Naphthalenes via Platinum-Catalyzed Hydroarylation of Aryl Enynes

  作者 KANG DONGJIN; KIM JINSIK; OH SUSUNG; LEE PHIL HO  
  选自 期刊  Organic Letters;  卷期  2012年14-22;  页码  5636-5639  
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[摘要]An efficient synthetic method of functionalized naphthalenes having hydrogen, alkyl, alkenyl, aryl, or heteroaryl groups on the 4-position and ethoxycarbonyl group on the 2-position was developed through selective Pt-catalyzed 6-endo intramolecular hydroarylation of ethyl (E)-2-ethynyl/alkynyl cinnamates.

 
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