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[摘要]:Functionalized aryl- or heteroarylmagnesium reagents, prepared from the corresponding bromides or iodides using halogenmagnesium exchange or direct magnesium insertion in the presence of lithium chloride, reacted smoothly with N-fluorobenzenesulfonimide, (PhSO2)(2)NF, in the mixed solvent (4:1 CH2Cl2-perfluorodecalin) to give the corresponding aromatic fluorides in moderate to good yields. |
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