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Rapid and Convenient One-Pot Method for the Preparation of Alkali Metal Phosphinodiselenoates

  作者 ARTEMEV ALEXANDER V; MALYSHEVA SVETLANA F; GUSAROVA NINA K; TROFIMOV BORIS A  
  选自 期刊  Synthesis;  卷期  2010年-14;  页码  2463-2467  
  关联知识点  
 

[摘要]Alkali metal phosphinodiselenoates, R2PSe2M (R = aralkyl, hetaralkyl, Ph; M = Li, Na, K, Rb, Cs), were synthesized in high yields (up to 98%) by a three-component reaction of a secondary phosphine, elemental selenium, and an alkali metal hydroxide under mild conditions (ethanol, room temperature, 5 min).

 
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