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Nucleophilic Substitution of Fluorine Atoms in 2,6-Difluoro-3-(pyridin-2-yl)benzonitrile Leading to Soluble Blue-Emitting Cyclometalated Ir(III) Complexes

  作者 KOZHEVNIKOV VALERY N; DAHMS KATJA; BRYCE MARTIN R  
  选自 期刊  Journal of Organic Chemistry;  卷期  2011年76-12;  页码  5143-5148  
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[摘要]New functionalized phenylpyridine ligands and their derived heteroleptic cyclometalated Ir(III) complexes have been synthesized. The complexes possess a combination of important properties: (i) blue emission, (ii) good photoluminescence quantum yields, and (iii) good solubility in organic solvents, making them very attractive as phosphorescent dopant emitters for solution-processable light-emitting devices.

 
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