MoO2Cl2(dmf)(2)-Catalyzed Domino Reactions of omega-Nitro Alkenes to 3,4-Dihydro-2H-1,4-benzothiazines and Other Heterocycles

[摘要]：Using the transformation of allyl 2-nitrophenyl thioethers to 3,4-dihydro-2H-1,4-benzothiazines as an example the reductive cyclization of omega-nitroalkenes to saturated N-heterocycles can be performed highly selective and with high yields if a combination of MoO2Cl2(dmf)(2) as a catalyst and Ph3P as reducing agent are employed.

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