An inorganic-organic composite framework with an unprecedented 3D heterometallic inorganic connectivity and white-light emission

[摘要]：The first example of an inorganic-organic composite framework with a 3D inorganic Cd-O-M (M = Cd, Rb) connectivity, featuring a unique {Cd7Rb}(n) helix and nanoscale {Cd16Rb4} and {Cd18Rb2} rings, has been constructed and structurally characterized. This compound exhibits white-light emission and a wavelength-dependent photochromic response.

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