Fluorinated 5-and 7-membered carbacycle motifs by reaction of difluorocarbene with acetylene ethers
[摘要]:The reaction of acetylene ethers with difluorocarbene (CF2), generated from the Ruppert-Prakash reagent, unexpectedly gave rise to co-produced fluorinated bicyclic [2.1.1]-hex-2-ene and cyclohepta-1,4-diene ring products.
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