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Negative-Ion Mass Spectra of Diterpene Alkaloids with the Keto Group in the 6-or 7-Position

  作者 Mavrodiev, D. V.; Abdullin, M. F.; Sainiev, D. A.; Nafikova, E. P.; Tsyrlina, E. M.; Mavrodiev, V. K.; Furlei, I. I.; Yunusov, M. S.  
  选自 期刊  HIGH ENERGY CHEMISTRY;  卷期  2012年46-2;  页码  73-78  
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[摘要]Processes resulting in the formation of negative ions by molecules of some diterpene alkaloids via resonance electron capture have been studied. The mass spectra of these compounds have a small number of lines represented largely by intense peaks in the thermal electron energy region and are due to electron capture onto the lower unoccupied molecular orbital, which is pi*-C=O or pi*-Ph-C=O in character.

 
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