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Encapsulation of Guests within a Gated Molecular Basket: Thermodynamics and Selectivity.

  作者 Wang, Bao-Yu;Bao, Xiaoguang;Stojanovic, Sandra;Hadad, Christopher M.;Badjic, Jovica D.;  
  选自 期刊  Organic Letters;  卷期  2008年10-23;  页码  5361-5364  
  关联知识点  
 

[摘要]structural, yet dynamic, feature of the host has been revealed to permit the formation of a transient enclosed space capable of contg. haloalkanes, whose size/shape, electronic and entropic attributes contributed to the thermodn. of binding. Markedly, the basket is capable of mediating the trafficking of a broad range of mols.

 
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