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Immobilization of oligostyrene-prolinol conjugates into polystyrene via electrospinning and applications of these fibers in catalysis.

  作者 Roeben, Caren;Stasiak, Michael;Janza, Birgit;Greiner, Andreas;Wendorff, Joachim H.;Studer, Armido;  
  选自 期刊  Synthesis;  卷期  2008年-14;  页码  2163-2168  
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[摘要]This paper reports the synthesis of prolinol-oligostyrene conjugates and their immobilization into a polystyrene matrix by using the electrospinning process. Via this approach fibers with a large surface area (fiber diam. of 1.2 mm) contg. the prolinol conjugate are readily obtained. The fibers are shown to be catalytically active in a test Michael reaction. The fibrous catalyst system can readily be removed from the reaction mixt. and be reused. However, a decrease of the catalyst activity was noticed upon recycling the fibrous catalyst systems.

 
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