A Facile Synthesis of alpha-Fluoro Ketones Catalyzed by [Cp*IrCl(2)](2)

[摘要]：Allylic alcohols are isomerized into enolates (enols) by [Cp*IrCl(2)](2). The enolates react with Selectfluor present in the reaction media. This method produces alpha-fluoro ketones as single constitutional isomers in high yields.

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