Synthesis of Fullerene-Fused Fluorine-Containing Lactones from the Radical Reaction of [60]Fullerene with Fluorinated Phenylacetic Acids

[摘要]：A series of fullerene-fused fluorinated lactones were prepared by the manganese(III) acetate mediated radical reaction of [60]fullerene (C-60) with fluorinated phenylacetic acids (ArFCH2COOH). Interestingly, the products which contain a 2-fluoro substituent on the benzene ring are mixtures of two stereoisomers due to the stereo and electronic effects of the ortho-fluorine atom.

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