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Metal-Free Electrocyclization at Ambient Temperature: Synthesis of 1-Arylcarbazoles

  作者 SAMANTA RAJARSHI; KULIKOV KATHARINA; STROHMANN CARSTEN; ANTONCHICK ANDREY P  
  选自 期刊  Synthesis;  卷期  2012年44-15;  页码  2325-2332  
  关联知识点  
 

[摘要]An efficient novel protocol for the construction of an hyellazole-inspired compound collection is described. Starting from 2,6-diarylacetanilides, the desired products were obtained using hypervalent iodine promoted electrocyclization. The mechanism of product formation was investigated through intramolecular competition experiments.

 
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