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C-[o-(p-TOLYL)SULFINYL]PHENYLNITRONES. SYNTHESIS AND REACTIVITY IN [3+2] DIPOLAR CYCLOADDITIONS

  作者 GARCIA RUANO JOSE LUIS; FRAILE ALBERTO; NUNEZ ALBERTO; ROSARIO MARTIN M; ALONSO INES  
  选自 期刊  Heterocycles;  卷期  2012年84-2;  页码  913-928  
  关联知识点  
 

[摘要]The synthesis of the title compounds and the results obtained in their reactions with different dipolarophiles is presented. Alkylidene malonates afford the best conversions and stereoselectivities, providing enantiomerically pure isoxazolidines easily transformed into interesting tricyclic structures with t-BuLi.

 
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