A Versatile and Highly Stereoselective Synthesis of Diethyl (1-Aminoalkyl)thiophosphonates

[摘要]：A series of chiral diethyl (1-aminoalkyl)thiophosplionates was synthesized in high yield and excellent enantioselectivity by nucleophilic addition of diethyl thiophosphonate to N-(tert-butylsulfinyl)imines under mild conditions. There is no evidence indicating that the reaction is influenced by electronic or steric effects of the substrates.

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