Highly Efficient, Regioselective, and Stereospecific Oxidation of Aliphatic C-H Groups with H2O2, Catalyzed by Aminopyridine Manganese Complexes

[摘要]：Aminopyridine manganese complexes [LMnII(OTf)(2)] having a similar coordination topology catalyze the oxidation of unactivated aliphatic C-H groups with H2O2, demonstrating excellent efficiency (up to TON = 970), site selectivity, and stereospecificity (up to >99%).

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