Novel Synthetic Approach to Arylboronates via Rhodium-Catalyzed Carbon-Cyano Bond Cleavage of Nitriles

[摘要]：A new rhodium-catalyzed method for preparing arylboronates from aryl cyanides through the cleavage of carbon-cyano bonds is described. This unprecedented transformation of nitriles allows the use of a cyano group as a boryl equivalent and the regioselective introduction of a boryl group at a late stage of the synthesis.

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