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Friedel-Crafts-Type Alkylation with Bromodifluoro(phenylsulfanyl)methane through alpha-Fluorocarbocations: Syntheses of Thioesters, Benzophenones and Xanthones

  作者 KUHAKARN CHUTIMA; SURAPANICH NAKIN; KAMTONWONG SIRIPORN; POHMAKOTR MANAT; REUTRAKUL VICHAI  
  选自 期刊  European Journal of Organic Chemistry;  卷期  2011年-29;  页码  5911-5918  
  关联知识点  
 

[摘要]Bromodifluoro(phenylsulfanyl)methane undergoes a Friedel-Crafts-type alkylation, through alpha-fluorocarbocations, with activated aromatic compounds yielding thioesters and/or benzophenones. The methodology has been applied to the synthesis of naturally occurring xanthone derivatives.

 
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