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Tetrabenzylhafnium as a New Organometallic Reagent for Imine Addition Resulting in alpha-Branched Amines

  作者 MEI HAIBO; JI XIAOYUN; HAN JIANLIN; PAN YI  
  选自 期刊  European Journal of Organic Chemistry;  卷期  2011年-29;  页码  5783-5786  
  关联知识点  
 

[摘要]Tetrabenzylhafnium has been explored as a new organometallic reagent for the imine addition reaction. This reagent tolerates a wide scope of imines, affording alpha-branched amines in excellent yields without the use of any additive or catalyst. This new reagent shows higher efficiency than that observed for classic Grignard and organolithium reagents.

 
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