CAN-Mediated Highly Regio- and Stereoselective Oxidation of Vinylidenecyclopropanes: A Novel Method for the Synthesis of Unsymmetrical Divinyl Ketone and Functional Enone Derivatives.

[摘要]：CAN-mediated oxidative rearrangement of various vinylidenecyclopropanes under mild conditions generates unsym. divinyl ketone and functional enone derivs. in moderate to good yields with excellent regio- and stereoselectivities. The reaction mechanism was investigated on the basis of an oxygen-18 tracer expt.

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