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[摘要]：A novel series of nanocomposite hydrogels (MD-NC gels), consisting of inorganic clay (hectorite) and specific copolymers with different chemical affinities for water, i.e., copolymers composed of hydrophobic (2-methoxyethyl acrylate: MBA) and hydrophilic (N,N-dimethylacrylamide: DMAA) units, were prepared by in situ free-radical polymerization in aqueous media at 20 C. MD-NC gels showed outstanding stimuli sensitivities in response to changes in temperature, pH, salt concentration, and solvents in the surrounding aqueous solution as well as excellent, composition-dependent mechanical properties, such as a large elongations at break (>= 1000%) and high strengths and moduli. After drying, the gels were changed into transparent, soft nanocomposites (MD-NCs) with high mechanical toughness and safety in in vitro cytotoxicity tests. The clay morphology in MD-NCs gradually changed on increasing the molar ratio of DMAA from a clay shell network of 20 nm thickness to a uniform dispersion of exfoliated clay platelets in a polymer matrix. |
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