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Cyclic Alkenyl Boronic Half Acid Synthesis and Applications

  作者 MCNULTY LUANNE; KOHLBACHER KRIS; BORIN KATIE; DODD BRYAN; BISHOP JENI; FULLER LINDSEY; WRIGHT ZACH  
  选自 期刊  Journal of Organic Chemistry;  卷期  2010年75-17;  页码  6001-6004  
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[摘要]The synthesis of cyclic alkenyl boronic half acids from vinyl and propenyl boronic esters and homoallylic alcohols by ring-closing metathesis is reported. The method is compatible with both conventional and microwave heating and comparable yields are obtained under both conditions. The cyclic alkenyl boronic acids participate in Suzuki-Miyaura coupling reactions in good yields.

 
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