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Ruthenium-Catalyzed C-H Oxygenation on Aryl Weinreb Amides

  作者 YANG FANZHI; ACKERMANN LUTZ  
  选自 期刊  Organic Letters;  卷期  2013年15-3;  页码  718-720  
  关联知识点  
 

[摘要]Versatile ruthenium catalysts enabled unprecedented C-H bond oxygenations of aryl Weinreb amides with ample scope under exceedingly mild reaction conditions, thereby also giving access to valuable ortho-hydroxylated aldehydes. Mechanistic studies provided strong support for a kinetically relevant C-H bond activation.

 
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