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Click chemistry in carbon nanoreactors

  作者 RANCE GRAHAM A; SOLOMONSZ WILLIAM A; KHLOBYSTOV ANDREI N  
  选自 期刊  Chemical Communications;  卷期  2013年49-11;  页码  1067-1069  
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[摘要]Copper-nanoparticle catalytic centres anchored at the graphitic step-edges within hollow carbon nanoreactors exhibit superior activity and stability in cycloaddition reactions as compared to catalytic centres outside the nanoreactors. Nanoscale confinement enables efficient recycling of the catalyst in preparative-scale synthesis without significant changes in activity.

 
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