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Sequence Stereoisomerism in Calixarene-Based Pseudo[3]rotaxanes

  作者 TALOTTA CARMEN; GAETA CARMINE; PIERRO TERESA; NERI PLACIDO  
  选自 期刊  Organic Letters;  卷期  2011年13-8;  页码  2098-2101  
  关联知识点  
 

[摘要]Two calix[6]arene directional wheels can be ordered in the right stereosequence by their through-the-annulus threading with a rationally designed bis(benzylalkylammonium) axle. These stereoisomeric pseudo[3]rotaxanes can be considered as a minimal "informational system" because the "written information" on the thread is transferred to a specific sequence stereoisomer.

 
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