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A stereoselective approach for the total synthesis of clonostachydiol.

  作者 Yadav, J. S.;Swamy, T.;Reddy, B. V. Subba;  
  选自 期刊  SYNLETT;  卷期  2008年-18;  页码  2773-2776  
  关联知识点  
 

[摘要]A stereoselective synthesis of clonostachydiol is accomplished using readily available (?-epichlorohydrin as a precursor. The synthesis involves direct and straightforward reactions such as Sharpless asym. epoxidn., iodination, stereoselective opening of epoxide with allylmagnesium chloride, and Sharpless asym. dihydroxylation.

 
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