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Light Emission of [10]Cyclophenacene through Energy Transfer from Neighboring Carbazolylphenyl Dendrons.

  作者 Zhang, Xiaoyong;Matsuo, Yutaka;Nakamura, Eiichi;  
  选自 期刊  Organic Letters;  卷期  2008年10-18;  页码  4145-4147  
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[摘要]Photochemistry, and Photographic and Other Reprographic A dendritic deca(carbazolylphenyl)[60]fullerene bearing a cyclic benzenoid core was synthesized. The photophys. studies indicated that intramol. energy transfer and electron transfer took place from the linked carbazolylphenyl moieties to the core-cyclic benzenoid moiety. The fluorescence quantum yield of the deca-adduct was detd. to be 0.21 in toluene. Rich photophys. functions and their dendritic structures suggest that the photoactive deca-adducts will serve as luminescent scaffolds in materials application.

 
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