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[摘要]:The first oxoammonium salt mediated formation of C-C bonds from benzylic C(sp(3))-H bonds adjacent to an oxygen or nitrogen atom by dehydrogenative coupling with enolizable carbonyls has been developed The use of these oxidants in combination with catalytic amounts of Fe(OTf)(2), as Lewis acid allows the reaction to be carried out under mild conditions, leading to the corresponding coupling products in moderate to good yields. |
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