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Computational Study of C-H Insertion Reactions with Ethyl Bromodiazoacetate

  作者 BONGE HANNE THERESE; HANSEN TORE  
  选自 期刊  European Journal of Organic Chemistry;  卷期  2010年-23;  页码  4355-4359  
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[摘要]A computational study of C-H insertion reactions between ethyl bromodiazoacetate and three different substrates is presented The mechanism of the C-H insertion is shown to be substrate dependent, the reaction follows either a concerted mechanism or a two-step mechanism in which complete hydride transfer precedes C-C bond formation

 
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