【文章名】Synthesis of 5-(adamantan-1-yl)-4,4-dimethyl-1-(3-oxyphenyl)-2,6,7-trioxabicyclo[3.2 .0]heptanes and their base-induced chemiluminescent decomposition in liquid/solid phase.
Synthesis of 5-(adamantan-1-yl)-4,4-dimethyl-1-(3-oxyphenyl)-2,6,7-trioxabicyclo[3.2 .0]heptanes and their base-induced chemiluminescent decomposition in liquid/solid phase.
[摘要]：Singlet oxygenation of 4-(adamantan-1-yl)-5-(3-hydroxyphenyl)-1,2-dihydrofuran effectively gave bicyclic dioxetane I as crystals with a high m.p. Dioxetane I decompd. rapidly accompanied by the emission of blue light, when treated with Bu4NF (TBAF) in DMSO or MeCN. The chemiluminescence efficiency for I was as high as those for the tert-Bu analog. In addn. to chemiluminescent decompn. in a liq. phase, a finely emitted blue light upon heating at 80-110?while maintaining a solid state.
