Diethylaluminum Iodide Promoted Morita-Baylis-Hillman Reaction of D-Glucose-Derived Densely O-Functionalized Cyclopentenone: Route to alpha-C-Branched Densely Functionalized Cyclic Enones

[摘要]：MoritaBaylisHillman (MBH) reaction of D-glucose-derived highly O-functionalized cyclopentenone is described for the first time. The MBH reaction of cyclopentenone with different aldehydes in the presence of diethylaluminum iodide proceeded smoothly in moderate to good yields. Promoters such as organic, inorganic, or Lewis bases and an aqueous medium are not suitable conditions for the MBH reaction of highly O-functionalized cyclopentenones with aldehydes.

[全文传递流程]：

一般上传文献全文的时限在1个工作日内