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Regiospecific Azidoiodination of Alkenes with Sodium Periodate, Potassium Iodide, and Sodium Azide: A High-Yield Synthesis of beta-Iodoazides

  作者 CHOUTHAIWALE PANDURANG V; KARABAL PRATIBHA U; SURYAVANSHI GURUNATH; SUDALAI ARUMUGAM  
  选自 期刊  Synthesis;  卷期  2010年-22;  页码  3879-3882  
  关联知识点  
 

[摘要]The combination of sodium periodate, potassium iodide, and sodium azide has been found to be an efficient, simple, and inexpensive reagent system for azidoiodination of alkenes. The regiospecific 1,2-azidoiodination proceeds in an anti-Markovnikov fashion to produce beta-iodoazides in excellent yields.

 
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