Simple Synthesis of N-Aryl-2-nitrosoanilines in the Reaction of Nitroarenes with Aniline Anion Derivatives

[摘要]：Anions generated from primary arylamines react with substituted nitrobenzenes to form sigma(H)-adducts, which, under basic reaction conditions, undergo transformation to N-aryl-2-nitroso-amines. Competitive substitution of reactive halogens in the nitro-arenes, which is observed in certain cases, can be controlled by the solvent selected.

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