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Direct Addition of Functionalized Organozinc Reagents to Carbon Dioxide, Ketones, and Aldehydes in the Presence of MgCl2

  作者 BERNHARDT SEBASTIAN; METZGER ALBRECHT; KNOCHEL PAUL  
  选自 期刊  Synthesis;  卷期  2010年-22;  页码  3802-3810  
  关联知识点  
 

[摘要]A variety of functionalized organozinc reagents undergo smooth addition reactions at ambient temperature to carbon dioxide, ketones, and aldehydes in the presence of stoichiometric amounts of MgCl2. Several reactions were performed on a 20 mmol scale.

 
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