Asymmetric 5-endo chloroetherification of homoallylic alcohols toward the synthesis of chiral beta-chlorotetrahydrofurans

[摘要]：An asymmetric 5-endo chloroetherification of homoallylic alcohols is successfully developed that employs an easily available quaternary ammonium salt derived from cinchonine as a conventional organocatalyst. This approach provides ready access to beta-chlorotetrahydrofurans in high enantioselectivities.

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