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Palladium(II)-Catalyzed Dehydrogenative Alkenylation of Cyclic Enaminones via the Fujiwara-Moritani Reaction

  作者 YU YIYUN; NIPHAKIS MICAH J; GEORG GUNDA I  
  选自 期刊  Organic Letters;  卷期  2011年13-21;  页码  5932-5935  
  关联知识点  
 

[摘要]A new Pd(II)-catalyzed dehydrogenative alkenylation reaction involving two alkenes was developed. A variety of nonaromatic, cyclic enaminones were successfully coupled to primary and secondary alkenes yielding a series of unique 1,3-dienes. The generality of this transformation presents a useful strategy for directly cross-coupling alkenes and offers an attractive new approach to functionallze enaminones.

 
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