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Synthesis of Monoacylated Derivatives of 1,2-Cyclohexanediamine. Evaluation of their Catalytic Activity in the Preparation of Wieland-Miescher Ketone

  作者 FUENTES DE ARRIBA ANGEL L; SEISDEDOS DAVID G; SIMON LUIS; ALCAZAR VICTORIA; RAPOSO CESAR; MORAN JOAQUIN R  
  选自 期刊  Journal of Organic Chemistry;  卷期  2010年75-23;  页码  8303-8306  
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[摘要]Ureas, carbamoyl derivatives, amides, and sulfonamides can be easily prepared from the strained (R,R)-cylohexanediamine urea (1) in high yield, leaving a free amino group that shows good catalytic activity in intramolecular aldol condensations. The preparation of Wieland-Miescher ketone has been studied with these catalysts.

 
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