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A Mild One-Pot Method for Conversion of Various Steroidal Secondary Alcohols into the Corresponding Olefins

  作者 KUMAR RAJU RANJITH; HAVELI SHRUTISAGAR DATTATRAYA; KAGAN HENRI B  
  选自 期刊  SYNLETT;  卷期  2011年-12;  页码  1709-1712  
  关联知识点  
 

[摘要]The addition of Tf(2)O to some hydroxy steroids in the presence of excess base directly leads to steroidal olefins. This methodology is useful for the one-pot synthesis of Delta(2)- or Delta(3)-steroids under mild conditions from the corresponding alcohols.

 
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