Formal Total Synthesis of (-)-Raphidecursinol B

[摘要]：An efficient enantioselective formal total synthesis of antimalarial natural product (-)-raphidecursinol B along with its all stereoisomers is described from commercially available 3,4,5-trimethoxybenzaldehyde using the Sharpless asymmetric dihydroxylation, regioselective alpha-tosylation, epoxide opening and Mitsunobu reaction as the key reaction steps.

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