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Metal-Free Synthesis of Imido Derivatives by Direct Oxidation of alpha-Amido Sulfones

  作者 MARTINELLI FABIO; PALMIERI ALESSANDRO; PETRINI MARINO  
  选自 期刊  European Journal of Organic Chemistry;  卷期  2010年-26;  页码  5085-5089  
  关联知识点  
 

[摘要]Oxidation of alpha-amidoaryl sulfones with m-chloroperoxybenzoic acid under mild conditions readily provides the corresponding imides in satisfactory yields. The overall process probably involves formation of an N-acyliminium ion intermediate, which by attack of the peroxyacid anion generates the final imido derivatives.

 
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