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Biomimetic Synthesis of Polycyclic Polyprenylated Acylphloroglucinol Natural Products Isolated from Hypericum papuanum

  作者 GEORGE JONATHAN H; HESSE MICHA D; BALDWIN JACK E; ADLINGTON ROBERT M  
  选自 期刊  Organic Letters;  卷期  2010年12-15;  页码  3532-3535  
  关联知识点  
 

[摘要]Biomimetic syntheses of three polycylic polyprenylated acylphloroglucinol natural products isolated from Hypericum papuanum, ialibinone A, ialibinone B, and hyperguinone B, have been accomplished by selective oxidative cyclizations of the proposed biosynthetic precursor 5, which was synthesized from phloroglucinol in three steps.

 
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