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Dracotanosides A-D, Spermidine Glycosides from Dracocephalum tanguticum: Structure and Amide Rotational Barrier

  作者 Wang, SQ; Ren, DM; Xiang, F; Wang, XN; Zhu, CJ; Yuan, HQ; Sun, LM; Lv, BB; Sun, XJ; Lou, HX  
  选自 期刊  Journal of natural products;  卷期  2009年72-6;  页码  1006-1010  
  关联知识点  
 

[摘要]Four new spermidine glycosides, dracotanosides A-D (1-4), have been isolated from Dracocephalum tanguticum. These molecules represent the first spermidine glycosides from this plant genus. The structures, including absolute configurations, were determined by spectroscopic and chemical methods. The amide bond rotational barrier of aglycone 1a was calculated by density functional theory (DFT) computation.

 
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