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Reversing the Enantioselectivity of a Peptidic Catalyst by Changing the Solvent

  作者 MESSERER MATTHIAS; WENNEMERS HELMA  
  选自 期刊  SYNLETT;  卷期  2011年-4;  页码  499-502  
  关联知识点  
 

[摘要]The enantioselectivity of the peptidic catalyst H-Pro-Pro-Asp-NH(CH2) 11CH3 is reversed in different solvents. One enantiomer forms preferentially in pure DMSO or MeOH, whereas the other is preferentially formed in mixtures of water with DMSO or MeOH.

 
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