Intramolecular sigma-Bond Metathesis Between Carbon-Carbon and Silicon-Silicon Bonds

[摘要]：An intramolecular sigma-bond metathesis between carbon carbon and silicon silicon bonds took place on treatment of a disilane tethered to a cyclobutanone with a palladium(0) catalyst, furnishing a silaindane skeleton as well as an acylsilane functionality at once.

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