Unexpected Copper-Catalyzed Aerobic Oxidative Cleavage of C(sp(3))-C(sp(3)) Bond of Glycol Ethers

[摘要]：An unexpected Cu-catalyzed oxidative cleavage of the C(sp(3))-C(sp(3)) bond in glycol ethers by using air or molecular oxygen as the terminal stoichiometric oxidant is demonstrated. As a result, the corresponding alpha-acyloxy ethers and formates of 1,2-ethanediol are formed by direct coupling of carboxylic acids and aldehydes with glycol ethers under the reaction conditions. This method represents the first example of Cu-catalyzed aerobic cleavage of saturated C-C bond in ethers.

[全文传递流程]：

一般上传文献全文的时限在1个工作日内