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Relation between Self-Diffusion and Viscosity in Dense Liquids: New Experimental Results from Electrostatic Levitation

  作者 Brillo, J; Pommrich, AI; Meyer, A  
  选自 期刊  PHYSICAL REVIEW LETTERS;  卷期  2011年107-16;  页码  165902-165902  
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[摘要]By using the technique of electrostatic levitation, the Ni self-diffusion, density, and viscosity of liquid Zr(64)Ni(36) have been measured in situ with high precision and accuracy. The inverse of the viscosity, eta, measured via the oscillating drop technique, and the self-diffusion coefficient D, obtained from quasielastic neutron scattering experiments, exhibit the same temperature dependence over 1.5 orders of magnitude and in a broad temperature range spanning more than 800 K. It was found that D(eta) = const for the entire temperature range, contradicting the Stokes-Einstein relation.

 
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